HEAT TREATMENT OF METALS
Heat treatment is any one of a number of controlled heating and cooling operations used to bring about a desired change in the physical properties of a metal. Its purpose is to improve the structural and physical properties for some particular use or for future work of the metal. There are five basic heat treating processes: hardening, case hardening, annealing, normalizing, and tempering. Although each of these processes bring about different results in metal, all of them involve three basic steps: heating, soaking, and cooling.
Heating is the first step in a heat-treating process. Many alloys change structure when they are heated to specific temperatures. The structure of an alloy at room temperature can be either a mechanical mixture, a solid solution, or a combination solid solution and mechanical mixture.
A mechanical mixture can be compared to concrete. Just as the.sand and gravel are visible and held in place by the cement. The elements and compounds in a mechanical mixture are clearly visible and are held together by a matrix of base metal. A solid solution is when two or more metals are absorbed, one into the other, and form a solution. When an alloy is in the form of a solid solution, the elements and compounds forming the metal are absorbed into each other in much the same way that salt is dissolved in a glass of water. The separate elements forming the metal cannot be identified even under a microscope. A metal in the form of a mechanical mixture at room temperature often goes into a solid solution or a partial solution when it is heated. Changing the chemical composition in this way brings about certain predictable changes in grain size and structure. This leads to the second step in the heat treating process: soaking.
Once a metal part has been heated to the temperature at which desired changes in its structure will take place, it must remain at that temperature until the entire part has been evenly heated throughout. This is known as soaking. The more mass the part has, the longer it must be soaked.
After the part has been properly soaked, the third step is to cool it. Here again, the structure may change from one chemical composition to another, it may stay the same, or it may revert to its original form. For example, a metal that is a solid solution after heating may stay the same during cooling, change to a mechanical mixture, or change to a combination of the two, depending on the type of metal and the rate of cooling. All of these changes are predictable. For that reason, many metals can be made to conform to specific structures in order to increase their hardness, toughness, ductility, tensile strength, and so forth.
HEAT TREATMENT OF FERROUS METALS
All heat-treating operations involve the heating and cooling of metals, The common forms of heat treatment for ferrous metals are hardening, tempering, annealing, normalizing, and case hardening.
A ferrous metal is normally hardened by heating the metal to the required temperature and then cooling it rapidly by plunging the hot metal into a quenching medium, such as oil, water, or brine. Most steels must be cooled rapidly to harden them. The hardening process increases the hardness and strength of metal, but also increases its brittleness.
Steel is usually harder than necessary and too brittle for practical use after being hardened. Severe internal stresses are set up during the rapid cooling of the metal. Steel is tempered after being hardened to relieve the internal stresses and reduce its brittleness. Tempering consists of heating the metal to a specified temperature and then permitting the metal to cool. The rate of cooling usually has no effect on the metal structure during tempering. Therefore, the metal is usually permitted to cool in still air. Temperatures used for tempering are normally much lower than the hardening temperatures. The higher the tempering temperature used, the softer the metal becomes. High-speed steel is one of the few metals that becomes harder instead of softer after it is tempered.
Metals are annealed to relieve internal stresses, soften them, make them more ductile, and refine their grain structures. Metal is annealed by heating it to a prescribed temperature, holding it at that temperature for the required time, and then cooling it back to room temperature. The rate at which metal is cooled from the annealing temperature varies greatly. Steel must be cooled very slowly to produce maximum softness, This can be done by burying the hot part in sand, ashes, or some other substance that does not conduct heat readily (packing), or by shutting off the furnace and allowing the furnace and part to cool together (furnace cooling).
Ferrous metals are normalized to relieve the internal stresses produced by machining, forging, or welding. Normalized steels are harder and stronger than annealed steels. Steel is much tougher in the normalized condition than in any other condition. Parts that will be subjected to impact and parts that require maximum toughness and resistance to external stresses are usually normalized. Normalizing prior to hardening is beneficial in obtaining the desired hardness, provided the hardening operation is performed correctly. Low carbon steels do not usually require normalizing, but no harmful effects result if these steels are normalized. Normalizing is achieved by heating the metal to a specified temperature (which is higher than either the hardening or annealing temperatures), soaking the metal until it is uniformly heated, and cooling it in still air.
Case hardening is an ideal heat treatment for parts which require a wear-resistant surface and a tough core, such as gears, cams, cylinder sleeves, and so forth. The most common case-hardening processes are carburizing and nitriding. During the case-hardening process, a low-carbon steel (either straight carbon steel or low-carbon alloy steel) is heated to a specific temperature in the presence of a material (solid, liquid, or gas) which decomposes and deposits more carbon into the surface of a steel. Then, when the part is cooled rapidly, the outer surface or case becomes hard, leaving the, inside of the piece soft but very tough.
HEAT TREATMENT OF NONFERROUS METALS
Two types of heat-treating operations can be performed on nonferrous metals. They are annealing and solution heat treating.
Most nonferrous metals can be annealed. The annealing process consists of heating the metal to a specific temperature, soaking, and cooling to room temperature. The temperature and method of cooling depend on the type of metal. Annealing is often accomplished after various cold working operations because many nonferrous metals become hard and brittle after cold working. Also, annealing is used to remove the effects of solution heat treatment so that machining or working qualities can be improved.
SOLUTION HEAT TREATMENT
The tensile strength of many nonferrous alloys can be increased by causing the materials within the alloy to go into a solid solution and then controlling the rate and extent of return to an altered mechanical mixture. This operation is called solution heat treatment. After an alloy has been heated to a specified temperature, it is “quenched” or cooled rapidly, which traps the materials in the solid solution attained during the heating process. From this point, the process varies greatly depending on the metal. To be sure the materials in the alloy do not revert to their original configuration after a period of time, a process of aging or precipitation hardening must follow. In this process the materials in the alloy are allowed to change or to precipitate out of the solid solution.
This process occurs under controlled conditions so that the resultant grain structure will produce a greater tensile strength in the metal than in its original condition. Depending on the alloy, this precipitation process can also consist of simply aging the alloy at room temperature for a specified time and then air-cooling it; this is called artificial aging.
Aluminum alloys can be obtained in various conditions of heat treatment called temper designations. Figure 2-11, on page 2-9, shows the various temper designations and the process to which they apply. The term “strain-hardened” refers to aging or hardening that has been brought about by coldworking the alloy. “Stabilizing” refers to a particular aging process that freezes or stops the internal changes that normally would take place in the alloy at room temperature. Magnesium alloys can be subjected to all of the nonferrous heat treatments, but the different alloys within the series require different temperatures and times for the various processes. Copper alloys are generally hardened by annealing. The nickel alloys can also be annealed and certain types can be hardened by heat treatment. Likewise, titanium may be annealed (mostly relieve machining or cold-working stresses) but is not noticeably affected by heat treatment.
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